Sustainable synthesis of balsalazide and sulfasalazine based on diazotization with low concentrated nitrogen dioxide in air
D. Hofmann, E. Gans, J. Krüll, M. R. Heinrich, Chem. Eur. J. 2017, accepted
DOI: 10.1002/chem.201605359
Organic chemistry - more radical than ever before
M. R. Heinrich, Tetrahedron 2016, 72, 7655 (preface to the special issue on radical chemistry)
DOI: 10.1016/j.tet.2016.09.064
88 Strongly directing substituents in the radical arylation of substituted benzenes
J. Hofmann, T. Clark, M. R. Heinrich, J. Org. Chem. 2016, 81, 9785-9791
DOI: 10.1021/acs.joc.6b01840
87 Recent developments in intramolecular radical arylations of arenes and heteroarenes
J. Hofmann, M. R. Heinrich, Tetrahedron Lett. 2016, 57, 4334-4340 (short review)
DOI: 10.1016/j.tetlet.2016.08.034
86 4-Biphenylalanine- and 3-phenyltyrosine-derived hydroxamid acids as inhibitors of the JumonjiC domain-containing histone demethylase KDM4A
L. Morera, M. Roatsch, M. C. D. Fürst, I. Hoffmann, J. Senger,  M. Hau, H. Franz, R. Schüle, M. R. Heinrich, M. Jung,  ChemMedChem 2016, 11, 2063-2083
DOI: 10.1002/cmdc.201600218
Regioselective radical arylation of 3-hydroxypyridines
M. C. D. Fürst, L. Bock, M. R. Heinrich, J. Org. Chem. 2016, 81, 5752-5758
DOI: 10.1021/acs.joc.6b00894, highlighted on
Thermally induced carbohydroxylation of styrenes with aryldiazonium salts
S. Kindt, K. Wicht, M. R. Heinrich, Angew. Chem. Int. Ed. 2016, 55, 8744-8747
DOI: 10.1002/anie.201601656
Synthesis of 6-arylpyridin-3-ols via oxidative rearrangement of 5-arylfurfurylamines
M. C. D. Fürst, C. S. Sauer, T. Moriyama, A. Kamimura, M. R. Heinrich, Eur. J. Org. Chem. 2016, 3051-3055
DOI: 10.1002/ejoc.201600377
82 Radical arylation of tyrosine residues in peptides
S. K. Fehler, G. Pratsch, C. Östreicher, M. C. D. Fürst, M. Pischetsrieder, M. R. Heinrich, Tetrahedron 2016, 72, 7888-7893
DOI: 10.1016/j.tet.2016.04.084
81Hydrogen peroxide-promoted Mizoroki-Heck reactions of phenyldiazenes with acrylates, acrylamides and styrenes
R. Lasch, S. K. Fehler, M. R. Heinrich, Org. Lett. 2016, 18, 1586-1589
DOI: 10.1021/acs.orglett.6b00449
80Recent advances in Meerwein arylation chemistry
S. Kindt, M. R. Heinrich, Synthesis 2016, 48, 1597-1606 (short review)
DOI: 10.1055/s-0035-1561586
79Development of Photoactivatable Allosteric Modulators for the Chemokine Receptor CXCR3
T. H. Admas, V. Bernat, M. R. Heinrich, N. Tschammer, ChemMedChem 2016, 11, in press
DOI: 10.1002/cmdc.201500573
782,4-Diaminopyrimidines as dual ligands at the histamine H1 and H4 receptor – H1/H4-receptor selectivity
S. G. Hammer, S. Gobleder, F. Naporra, H.-J. Wittmann, S. Elz, M. R. Heinrich, A. Strasser, Bioorg. Med. Chem. Lett. 201626, 292-300
DOI: 10.1016/j.bmcl.2015.12.035
77Base-induced radical carboamination of non-activated alkenes with aryldiazonium salts
S. Kindt, K. Wicht, M. R. Heinrich, Org. Lett. 2015, 17, 6122-6125
DOI: 10.1021/acs.orglett.5b03143
76 Denitrification combined with diazotization of anilines and the synthesis of 4’ chlorobiphenyl-2,5-diamine and 1-chloro-4-iodobenzene
D. Hofmann, J. Hofmann, L. Hofmann, L.-E. Hofmann, M. R. Heinrich, Org. Process Res. Dev. 2015, 19, 2075-2084
DOI: 10.1021/acs.oprd.5b00298
75Schnelle und effiziente Herstellung vielseitig einsetzbarer 18F-markierter Vorläufer für die Synthese radiomarkierter Verbindungen
S. K. Fehler, S. Maschauer, O. Prante, M. R. Heinrich, DE102014017352A1
74Zinc-mediated allylation and benzylation of phenylazocarboxylic esters
R. Lasch, M. R. Heinrich, J. Org. Chem. 2015, 80, 10412-10420
DOI: 10.1021/acs.joc.5b01978
73Oxidative nitration of styrenes for the recycling of low-concentrated nitrogen dioxide in air
D. Hofmann, C. de Salas,  M. R. Heinrich, ChemSusChem 2015, 8, 3167-3175
DOI: 10.1002/cssc.201500188
72Switching and conformational fixation of amides through proximate positive charges
A. L. Bartuschat, K. Wicht, M. R. Heinrich, Angew. Chem. Int. Ed. 201554, 10294–10298
DOI: 10.1002/ange.201502474; DOI: 10.1002/anie.201502474
71Cycloadditions to phenylazocarboxylic esters: a new access to highly substituted triazoles
R. Lasch, M. R. Heinrich, Tetrahedron 2015, 71, 4282-4295
DOI: 10.1016/j.tet.2015.04.078
70Ligand biased and probe-dependend modulation of the chemokine receptor CXCR3 signaling by negative allosteric modulators
V. Bernat, R. Brox, M. R. Heinrich, Y. Auberson, N. Tschammer, ChemMedChem 2015, 10, 556-574
DOI: 10.1002/cmdc.201402507
69Fluoro-substituted phenylazocarboxamides: dopaminergic behavior and N-arylating properties for irreversible binding
A. L. Bartuschat, T. Schellhorn, H. Hübner, P. Gmeiner, M. R. Heinrich, Bioorg. Med. Chem. 2015, 23, 3938-3947
DOI: 10.1016/j.bmc.2014.12.012
68From a natural product to aryl radical chemistry
S. K. Fehler, M. R. Heinrich, Synlett 2015, 580-603 (account article)
DOI: 10.1055/s-0034-1378945
67Synthesis of dibenzo[c,e][1,2]diazocines - a new group of eight-membered cyclic azo compounds
T. Nokubi, S. Kindt, T. Clark, A. Kamimura, M. R. Heinrich, Tetrahedron Lett. 2015, 56, 316-320
DOI: 10.1016/j.tetlet.2014.11.064
66Synthesis and evaluation of fluoro substituted pyridinylcarboxamides and their phenylazo analogues as potential dopamine D3 receptor PET ligands
N. Nebel, S. Maschauer, A. L. Bartuschat, S. K. Fehler, H. Hübner, P. Gmeiner, T. Kuwert, M. R. Heinrich, O. Prante, C. Hocke, Bioorg. Med. Chem. Lett. 2014, 24, 5399-5403
DOI: 10.1016/j.bmcl.2014.10.043
65Intermolecular radical carbofluorination of non-activated alkenes
S. Kindt, M. R. Heinrich, Chem. Eur. J. 2014, 20, 15344-15348
DOI: 10.1002/chem.201405229
64Synthesis of 7-arylquinolinones and 6-arylindoles from 3-aminobiphenyls through regioselective cyclization reactions
S. G. Hammer, M. R. Heinrich, Tetrahedron 2014, 70, 8114-8121
DOI: 10.1016/j.tet.2014.08.012
63The trapping of phenyldiazenes in cycloaddition reactions
S. K. Fehler, G. Pratsch, M. R. Heinrich, Angew. Chem. 2014, 126, 11543–11548, Angew. Chem. Int. Ed. 2014, 53, 11361-11365 
DOI: 10.1002/ange.201406175; DOI: 10.1002/anie.201406175
62Fixation and recycling of nitrogen monoxide through carbonitrosation reactions
C. de Salas, M. R. Heinrich, Green Chem. 2014, 16, 2982-2987
DOI: 10.1039/C3GC42432D
61Manganese(IV)-mediated hydroperoxyarylation of alkenes with arylhydrazines and dioxygen from air
S. Kindt, H. Jasch, M. R. Heinrich, Chem. Eur. J. 2014, 20, 6251–6255
DOI: 10.1002/chem.201400064
60Radiosynthesis and validation of 18F-FP-CMT, a phenyltropane with superior properties for imaging the dopamine transporter in living brain
P. Cumming, S. Maschauer, P. Riss, N. Tschammer, S. Fehler, M. R. Heinrich, T. Kuwert, O. Prante, J. Cereb. Blood Flow Metab. 2014, 34, 1148-1156
DOI: 10.1038/jcbfm.2014.63
59Oxidative radical arylation of anilines with arylhydrazines and dioxygen from air
J. Hofmann, H. Jasch, M. R. Heinrich, J. Org. Chem. 201479, 2314–2320
DOI: 10.1021/jo500063r
58Alanine-glyoxylate aminotransferase 2 (AGXT2) polymorphisms have considerable impact on methylarginine and beta-aminoisobutyrate metabolism in healthy volunteers
A. Kittel, F. Müller, J. König, M. Mieth, S. Bode-Böger, A. Kralj, M. R. Heinrich, M. F. Fromm, R. Maas, PLOS ONE 2014, 9, e88544
DOI: 10.1371/journal.pone.0088544
57Synthesis and biological evaluation of biphenyl amides that modulate the US28 receptor
A. Kralj, E. Kurt, N. Tschammer, M. R. Heinrich, ChemMedChem 2014, 9, 151-168
DOI: 10.1002/cmdc.201300369
56Fast and efficient 18F-labeling via [18F]fluorophenylazocarboxylic esters
S. Fehler, S. Maschauer, S. Höfling, A. Bartuschat, N. Tschammmer, H. Hübner, P. Gmeiner, O. Prante, M. R. Heinrich, Chem. Eur. J. 2014, 20, 370-375
DOI: 10.1002/chem.201303409
55Carbon-carbon bond forming reactions involving aryl radicals
S. Hammer, M. R. Heinrich, Comprehensive Organic Synthesis, 2014
ISBN-10: 0-080-97742-1; ISBN-13: 978-0-080-97742-3
54Method for synthesising aminobiphenyls using aryl hydrazines
M. Heinrich, H. Jasch, S. Höfling, WO2013132006
53Studies on the synthesis and biosynthesis of the fungal alkaloid necatorone
J. Carstens, M. R. Heinrich, W. Steglich, Tetrahedron Lett. 2013, 54, 5445-5447
DOI: 10.1016/j.tetlet.2013.07.118
52Enzymatic kinetic resolution and racemization of 2-(tetramethylpiperidine-1-oxyl)ethanols
A. Prechter, M. R. Heinrich, Eur. J. Org. Chem. 2013, 5585-5589
DOI: 10.1002/ejoc.201300661
51Development of flavonoid-based inverse agonists of the key signaling receptor US28 of Human Cytomegalovirus
A. Kralj, M.-T. Nguyen, N. Tschammer, N. Ocampo, Q. Gesiotto, M. R. Heinrich, O. Phanstiel,  J. Med. Chem. 2013, 56, 5019-5032
DOI: 10.1021/jm4003457
50Twofold carbon-carbon bond formation via intramolecular and intermolecular radical reactions of aryl diazonium salts
H. Jasch, Y. Landais, M. R. Heinrich, Chem. Eur. J. 2013, 19, 8411-8416
DOI: 10.1002/chem.201300354
49Process for the synthesis of aminobiphenylene
M. Heinrich, G. Pratsch, WO2012120003
48Verfahren zur Synthese von Aryloximen unter Verwendung von Stickstoffmonoxid
M. Heinrich, C. de Salas, DE102012010413
47Regioselective radical arylation of anilines with arylhydrazines
H. Jasch, J. Scheumann, M. R. Heinrich, J. Org. Chem. 2012, 77, 10699-10706
DOI: 10.1021/jo301980j
46Synthesis and Application of the First Radioligand Targeting the Allosteric Binding Pocket of Chemokine Receptor CXCR3
V. Bernat, M. R. Heinrich, P. Baumeister, A. Buschauer, N. Tschammer, ChemMedChem 2012, 7, 1481-1489
DOI: 10.1002/cmdc.201200184
45The Gomberg-Bachmann Reaction for the Arylation of Anilines with Aryl Diazotates
G. Pratsch, T. Wallaschkowski, M. R. Heinrich, Chem. Eur. J. 2012, 18. 11555-11559
DOI: 10.1002/chem.201200430
44Synthesis of (S)-(+)-cericlamine through lipase-catalyzed aminolysis of azo acetates
A. Prechter, H. Gröger, M. R. Heinrich, Org. Biomol. Chem. 2012, 10, 3384-3387
DOI: 10.1039/C2OB25247C
43Synthesis and biological evaluation of 3-aryltyramines as fragments binding to BACE-1 and BACE-2
S. K. Fehler, G. Pratsch, W. Huber, A. Gast, R. Hochstrasser, M. Hennig, M. R. Heinrich, Tetrahedron Lett. 2012, 53, 2189-2194
DOI: 10.1016/j.tetlet.2012.02.070
42Nucleophilic substitutions and radical reactions of phenylazocarboxylates
H. Jasch, S. B. Höfling, M. R. Heinrich, J. Org. Chem. 2012, 77, 1520-1532
DOI: 10.1021/jo202406k
41Modern developments in aryl radical chemistry
G. Pratsch, M. R. Heinrich, Topics in Current Chemistry 2012, 320 (Eds. M. R. Heinrich, A. Gansäuer), 33-60
DOI: 10.1007/128_2011_127
40Tin Hydrides and Functional Group Transformations
H. Jasch, M. R. Heinrich, Encyclopedia of Radicals in Chemistry, Biology and Materials, Eds. C. Chatgilialoglu, A. Studer, 1st ed., John Wiley & Sons, 2012
ISBN-10: 0-470-97125-8; ISBN-13: 978-0-470-97125-3
39Verfahren zur Herstellung von enantiomerenangereicherten Azoverbindungen, Aminoalkoholen und Aminosäuren mit einem quartären Kohlenstoffzentrum
F. Dietz, H. Gröger, M. Heinrich, A. Prechter, DE102011101183
38Identification of novel allosteric modulators for the G-protein coupled US28 receptor of human cytomegalovirus
A. Kralj, A. Wetzel, S. Mahmoudian, T. Stamminger, N. Tschammer, M. R. Heinrich, Bioorg. Med. Chem. Lett. 2011, 21, 5446-5450
DOI: 10.1016/j.bmcl.2011.06.120
37Radical carbonitrosation and recycling of the waste gas nitrogen monoxide
C. de Salas, O. Blank, M. R. Heinrich, Chem. Eur. J. 2011, 17, 9306-9310
DOI: 10.1002/chem.201101565
36Hydrogen peroxide and arenediazonium salts as reagents for a radical Beckmann-type rearrangement
A. Prechter, M. R. Heinrich, Synthesis 2011, 10, 1515-1525
DOI: 10.1055/s-0030-1260006
35Radical arylation of tyrosine and its application in the synthesis of a highly selective neurotensin receptor 2 ligand
G. Pratsch, J. F. Unfried, J. Einsiedel, M. Plomer, H. Hübner, P. Gmeiner, M. R. Heinrich, Org. Biomol. Chem. 2011, 9, 3746-3752.
DOI: 10.1039/c1ob05292f
34Hydroxy- and aminophenyl radicals from arenediazonium salts
G. Pratsch, C. A. Anger, K. Ritter, M. R. Heinrich, Chem. Eur. J. 2011. 17, 4104-4108
DOI: 10.1002/chem.201003713
33Nitrogen-centered radical scavengers
S. B. Höfling, M. R. Heinrich, Synthesis 2011, 173-189
DOI: 10.1055/s-0030-1258305
32Chiral azo compounds: Enantioselective analysis and transformations into β-amino alcohols and α-amino acidswith a quaternary stereocenter
F. R. Dietz, A. Prechter, H. Gröger, M. R. Heinrich, Tetrahedron Lett. 2010, 52, 655-657
DOI: 10.1016/j.tetlet.2010.11.137
31Method for arylation ring-substituted phenols and phenylethers
M. Heinrich, A. Wetzel, WO2010112211
30Method for producing 3-aminobiphenylene
M. Heinrich, A. Wetzel, WO2010037531
29Method for producing aminobiphenylene
M. Heinrich, A. Wetzel, M. Keil, M. Rack, T. Ziercke, WO201000856
28Synthesis, biological evaluation and radiolabeling by 18F-fluoroarylation of a dopamine D3 selective ligand as prospective imaging probe for PET
S. B. Höfling, S. Maschauer, H. Hübner, P. Gmeiner, H.-J. Wester, O. Prante, M. R. Heinrich, Bioorg. Med. Chem. Lett. 2010, 20, 6933-6937
DOI: 10.1016/j.bmcl.2010.09.142
274-Substituted tert-butyl phenylazocarboxylates - synthetic equivalents for the para-phenyl radical cation
S. B. Höfling, A. L. Bartuschat, M. R. Heinrich, Angew. Chem. 2010, 122, 9963-9966, Angew. Chem. Int. Ed. 201049, 9769-9772
DOI: 10.1002/ange.201004508; DOI: 10.1002/anie.201004508
26Radical arylation of phenols, phenyl ethers, and furans
A. Wetzel, G. Pratsch, R. Kolb, M. R. Heinrich, Chem. Eur. J. 2010, 16, 2547-2556
DOI: 10.1002/chem.200902927
25Hydroperoxides and aryl diazonium salts as reagents for the functionalization of non-activated olefins
O. Blank, N. Raschke, M. R. Heinrich, Tetrahedron Lett. 2010, 51, 1758-1760
DOI: 10.1016/j.tetlet.2010.01.098
24Intermolecular olefin functionalizations involving aryl radicals generated from arenediazonium salts
M. R. Heinrich, Chem. Eur. J. 2009, 15, 820-833
DOI: 10.1002/chem.200801306
23Synthesis of amino- and hydroxybiphenyls by a radical chain reaction of arenediazonium salts
A. Wetzel, V. Ehrhardt, M. R. Heinrich, Angew. Chem. 2008, 120, 9270-9273, Angew. Chem. Int. Ed. 2008, 47, 9130-9133
DOI: 10.1002/ange.200803785; DOI: 10.1002/anie.200803785
22Radiochemical [18F]fluoroarylation of unsaturated α-, β- and γ-amino acids, application to a radiolabeled derivate of baclofen
S. B. Höfling, C. Hultsch, H.-J. Wester, M. R. Heinrich, Tetrahedron 2008, 64, 11846-11851
DOI: 10.1016/j.tet.2008.07.117
21Radical carbodiazenylation – a convenient and effective method to achieve carboamination of non-activated olefins
O. Blank, A. Wetzel, D. Ullrich, M. R. Heinrich, Eur. J. Org. Chem. 2008, 3179-3189
DOI: 10.1002/ejoc.200800250
20Radical fluoroarylation in radiochemical synthesis
C. Hultsch, O. Blank, H.-J. Wester, M. R. Heinrich, Tetrahedron Lett. 2008, 49, 1881-1883
DOI: 10.1016/j.tetlet.2007.12.128
19Allylation and vinylation of aryl radicals generated from diazonium salts
M. R. Heinrich, O. Blank, D. Ullrich, M. Kirschstein, J. Org. Chem. 2007, 72, 9609-9616
DOI: 10.1021/jo701717k
18Intermolecular radical carboaminohydroxylation of olefins with aryl diazonium salts and TEMPO
M. R. Heinrich, A. Wetzel, M. Kirschstein, Org. Lett. 2007, 9, 3833-3835, Synfacts 2007, 1303
DOI: 10.1021/ol701622d
17Synthesis of 2-fluorotetralones by oxidative radical cyclization of α-fluoroacetophenones and olefins
M. R. Heinrich, Tetrahedron Lett. 2007, 48, 3895-3900
DOI: 10.1016/j.tetlet.2007.03.128
16Oxidative and reductive carbodiazenylation of nonactivated olefins
M. R. Heinrich, O. Blank, A. Wetzel, J. Org. Chem. 2007, 72, 476-484
DOI: 10.1021/jo061919p
15A new approach to the stereoselective carbodiazenylation of olefins by macrocyclization
M. R. Heinrich, O. Blank, A. Wetzel, Synlett 2006, 3352-3354
DOI: 10.1055/s-2006-951556
14Carbodiazenylation of olefins by radical iodine transfer and addition to arenediazonium salts
O. Blank, M. R. Heinrich, Eur. J. Org. Chem. 2006, 4331-4334
13Reductive carbodiazenylation of nonactivated olefins via aryl diazonium salts
M. R. Heinrich, O. Blank, S. Wölfel, Org. Lett. 2006, 8, 3323-3325, Synfacts 2006, 1045
DOI: 10.1021/ol0611393
12Photochemical generation and trapping of radicals from bisphenyl carbodiazone
M. R. Heinrich, M. Kirschstein, Tetrahedron Lett. 2006, 47, 2115-2118
DOI: 10.1016/j.tetlet.2006.01.128
11Generation and ring opening of aziridine N-carbonyl radicals
M. R. Heinrich, I. Pérez-Martín, S. Z. Zard, Chem. Commun. 2005, 5928-5930
DOI: 10.1039/b512956g
10A convergent approach to γ-carbonyl vinyl boronates
M. R. Heinrich, L. A. Sharp, S. Z. Zard, Chem. Commun. 2005, 3077-3079
DOI: 10.1039/b502885j
9Generation and intermolecular capture of cyclopropylacyl radicals
M. R. Heinrich, S. Z. Zard, Org. Lett. 2004, 6, 4969-4972
DOI: 10.1021/ol047892i
8Enhancing the catalytic activity of 4-(dialkylamino)pyridines by conformational fixation
M. R. Heinrich, H. S. Klisa, H. Mayr, W. Steglich, H. Zipse, Angew. Chem. 2003, 115, 4975-4977, Angew. Chem. Int. Ed. 2003, 42, 4826-4828
DOI: 10.1002/ange.200352289; DOI: 10.1002/anie.200352289
7 Total synthesis of the marine alkaloid halitulin
M. R. Heinrich, W. Steglich, M. G. Banwell, Y. Kashman, Tetrahedron 2003, 59, 9239-9247
DOI: 10.1016/j.tet.2003.02.005
6Effective syntheses of quinoline-7,8-diol, 5-amino-L-DOPA, and 3-(7,8-dihydroxyquinolin-5-yl)-L-alanine
M. R. Heinrich, W. Steglich, Tetrahedron 2003, 59, 9231-9237
DOI: 10.1016/j.tet.2003.02.004
5 Revision of the structure of haliclorensin to (S)-7-methyl-1,5-diazacyclotetradecane and confirmation of the new structure by synthesis
M. R. Heinrich, Y. Kashman, P. Spiteller, W. Steglich, Tetrahedron 2001, 57, 9973-9978
DOI: 10.1016/S0040-4020(01)01020-1
4Synthesis of (-)-(3S)-1-(3-aminopropyl)-3-methylazacyclo-decane, the structure proposed for the marine alkaloid haliclorensin
M. R. Heinrich, W. Steglich, Tetrahedron Lett. 2001, 42, 3287-3289
DOI: 10.1016/S0040-4039(01)00435-X
3Novel approach to the chemical bath deposition of chalcogenide semiconductors
D. S. Boyle, A. Bayer, M. R. Heinrich, O. Robbe, P. O´Brien, Thin Solid Films 2000, 361/362, 150-154
DOI: 10.1016/S0040-6090(99)00789-0
2 Developing environmentally benign routes for semiconductor synthesis: improved approaches to  thesolution deposition of cadmium sulfide for solar cell applications
A. Bayer, D. S. Boyle, M. R. Heinrich, D. J. Otway, O. Robbe, P. O´Brien, Green Chemistry 2000, 2, 79-86
DOI: 10.1039/A909257I
1 A novel method for the synthesis of the ternary thin film semiconductor cadmium zinc sulfide from acidic chemical baths
D. S. Boyle, O. Robbe, D. P. Halliday, M. R. Heinrich, A. Bayer, P. O´Brien, D. J. Otway, M. D. G. Potter, Journal of Materials Chemistry 2000, 10, 2439-2441
DOI: 10.1039/B005544L